以邻菲罗啉衍生物2-（2-呋喃基）咪唑[4，5-f]1，10-邻菲罗啉（FIP）和己二酸（ADA）为配体，在水热条件下，合成配合物[Mn3（ADA）3（FIP）2]n（1）和[Co3（ADA）3（FIP）2]n（2），经元素分析、红外光谱、热重和X-射线单晶衍射等进行表征。1属三斜晶系，空间群p-1，晶胞参数a＝8.640（3）？，b＝10.229（4）？，c＝14.918（5）？，α＝98.636（6）°，β＝106.240（6）°，γ＝107.040（6）°，Z＝2，Dc＝1.659 g·cm－3；2属三斜晶系，空间群p-1，晶胞参数a＝8.695（2）？，b＝10.010（2）？，c＝14.800（4）？，α＝71.742（4）°，β＝73.540（4）°，γ＝73.402（4）（6）°，Z＝2，Dc＝1.713g·cm－3。1和2的结构相似，Mn（Co）（1）中心是被来自一个FIP的两个N原子和三个ADA的四个O原子所绑定，Mn（Co）（2）中心是被来自六个ADA的六个O原子配位，两个Mn（Co）中心展示了扭曲八面体的配位结构，配合物中存在氢键和π-π堆积等弱的分子间作用力CCDC：1：1486701；2：1486702。%Complexes[Mn3(ADA)3(FIP)2 ]n(1)and[Co3(ADA)3(FIP)2 ]n(2)were synthesized by hydrothermal method,using a-dipic acid(ADA)and 2-(furan-2-yl)-1H-imidazo[4,5-f][1,10]phenanthroline(FIP)of Phenanthroline Derivative as the ligand. They were characterized by elemental analysis,IR,TG and X-ray diffraction etc. 1 belongs to triclinic system and space group p-1.The cell parameters of 1 was a=8.640 (3 )?,b=10.229 (4 )?,c=14.918 (5 )?,α=98.636 (6 )° ,β=106.240 (6 )° ,γ=107.040(6)°,Z=2,Dc=1.659 g·cm-3;2 belongs to triclinic system and space group p-1.The cell parameters of 2 was a=8.695 (2)?,b=10.010(2)?,c=14.800(4)?,α=71.742(4)°,β=73.540(4)°,γ=73.402(4)(6)°,Z=2,Dc=1.713g·cm-3.The structure of 1 and 2 is similar. The center of Mn(Co)(1)is bound by four O from three ADA and two N from one FIP. The center of Mn(Co)(2)is coordinated by six O from six ADA. The center of two Mn(Co)shows the coordination structure of distorted octa-hedral. The accumulation of π-π,hydrogen bonding and other weak intermolecular interactions in the complex in existence.
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