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醇的选择性催化氧化研究进展

             

摘要

本文从均相催化、多相催化、光催化氧化及其纳米颗粒催化等角度阐述醇选择氧化到醛酮的进展.重点介绍了以过渡金属为催化剂的催化氧化体系,并概述近年来光催化及纳米颗粒催化在醇的氧化中的应用.绿色化学的兴起,使未来新能源、新材料的开发与应用具有广阔的前景.%In this paper, the progress of selective oxidation of alcohols to aldehyde or ketones was discussed from the perspectives of homogeneous catalysis, heterogeneous catalysis, photocatalytic oxidation and nanoparticle catalysis. The catalytic systems composed of transition metals are emphasized. Meanwhile, the application of photocatalysis and nanoparticle catalysis in the oxidation of alcohols in recent years was discussed. With the developing of green chemistry, the research of new energy and new catalytic materials are considered to be attractive in the future.

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