Six complexes of two series were studied as the catalyst precursors for CO/ethylene copolymerization by using catalytic evaluation method and EXAFS technique.The first series of the complexes has general formular (L)Pd(OCOCF3)2 in which L is DPPPr,DPPBu or DPPEt.The second series of the complexes has general formular (DPPPr)Pd(A)2 in which A- is CF3COO- ,P- CH3PhSO3- ,Cl- or CH3COO- .The results showed that suitable ligands have relatively strong coordination ability to palladium(Ⅱ ) center.Suitable anoins belonging to strong acids,have excellent stability on cationic palladium(Ⅱ ),and easy to leave away to give coordination vacant to comonomers.
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