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Geometries in Soft Matter From Geometric Frustration, Liquid Droplets to Electrostatics in Solution.

机译:从几何挫折,液滴到溶液中的静电,软物质中的几何形状。

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摘要

This thesis explores geometric aspects of soft matter systems. The topics covered fall into three categories: (i) geometric frustrations, including the interplay of geometry and topological defects in two dimensional systems, and the frustration of a planar sheet attached to a curved surface; (ii) geometries of liquid droplets, including the curvature driven instabilities of toroidal liquid droplets and the self-propulsion of droplets on a spatially varying surface topography; (iii) the study of the electric double layer structure around charged spherical interfaces by a geometric method. In (i), we study the crystalline order on capillary bridges with varying Gaussian curvature. Energy requires the appearance of topological defects on the surface, which are natural spots for biological activity and chemical functionalization. We further study how liquid crystalline order deforms flexible structured vesicles. In particular we find faceted tetrahedral vesicle as the ground state, which may lead to the design of supra-molecular structures with tetrahedral symmetry and new classes of nano-carriers. Furthermore, by a simple paper model we explore the geometric frustration on a planar sheet when brought to a negative curvature surface in a designed elasto-capillary system. In (ii), motivated by the idea of realizing crystalline order on a stable toroidal droplet and a beautiful experiment on toroidal droplets, we study the Rayleigh instability and the shrinking instability of thin and fat toroidal droplets, where the toroidal geometry plays an essential role. In (iii), by a geometric mapping we construct an approximate analytic spherical solution to the nonlinear Poisson-Boltzmann equation, and identify the applicability regime of the solution. The derived geometric solution enables further analytical study of spherical electrostatic systems such as colloidal suspensions.
机译:本文探讨了软物质系统的几何方面。涵盖的主题分为三类:(i)几何挫折,包括二维系统中几何和拓扑缺陷的相互作用,以及附着在曲面上的平面板的挫折; (ii)液滴的几何形状,包括环形液滴的曲率驱动的不稳定性以及在空间变化的表面形貌上液滴的自推进; (iii)通过几何方法研究带电球面周围的双电层结构。在(i)中,我们研究了具有变化的高斯曲率的毛细管桥上的晶体顺序。能源需要在表面上出现拓扑缺陷,这些缺陷是生物活性和化学功能化的自然点。我们进一步研究液晶顺序如何使柔性结构囊泡变形。特别地,我们发现多面体四面体囊泡为基态,这可能导致具有四面体对称性的超分子结构和新型纳米载体的设计。此外,通过一个简单的纸模型,我们探索了在设计的弹性毛细管系统中,当平面片材出现负曲率表面时的几何挫折感。在(ii)中,出于在稳定的环形液滴上实现晶体有序的想法以及对环形液滴进行漂亮的实验的动机,我们研究了瑞利不稳定性和薄且胖的环形液滴的收缩不稳定性,其中环形几何起着至关重要的作用。在(iii)中,通过几何映射,我们构造了非线性Poisson-Boltzmann方程的近似解析球面解,并确定了该解的适用范围。导出的几何解可以进一步分析球形静电系统(如胶体悬浮液)。

著录项

  • 作者

    Yao, Zhenwei.;

  • 作者单位

    Syracuse University.;

  • 授予单位 Syracuse University.;
  • 学科 Physics.;Plasma physics.
  • 学位 Ph.D.
  • 年度 2012
  • 页码 187 p.
  • 总页数 187
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

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