首页> 外文会议>The Twelfth International Conference Additives 2003: Bringing New Value to Plastics Apr 14-16, 20036-9, 2003 San Francisco, California >BREAKTHROUGH POLYMER FINISHING TECHNOLOGY: Manufacturing Productivity and Polymer Performance Enhancements
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BREAKTHROUGH POLYMER FINISHING TECHNOLOGY: Manufacturing Productivity and Polymer Performance Enhancements

机译:突破性的聚合物精加工技术:提高生产效率和聚合物性能

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摘要

The viscosity of polymers can be reduced at typical molding stresses and temperatures by the addition of a small amount (≤ 2 percent by weight) of a micron-scale solid. Although many solids may exhibit some effect on polymer viscosity, naturally occurring, non-toxic, amorphous aluminosilicate glass is the only solid that is effective over a wide range of polymer compositions and temperatures while at the same time having no demonstrable effect on nucleation of semi-crystalline polymers. Extensive research on poly(propylene), used as a representative polymer, indicates that rheo logic properties described herein are dependent on particle composition, size range and concentration. The effect of the solid on the liquid polymer can thus be selected depending on the chosen particle characteristics. For most finishing applications, the practical benefit of the solid additive includes increased productivity, but may also include lower molding temperature, increased mechanical properties of the finished polymer, improved dispersion of additives, and better fit and finish of the article.
机译:通过添加少量(≤2重量%)的微米级固体,可以在典型的成型应力和温度下降低聚合物的粘度。尽管许多固体可能会对聚合物粘度产生某些影响,但天然存在的无毒无定形硅铝酸盐玻璃是唯一在多种聚合物组成和温度范围内均有效的固体,同时对半结晶成核没有明显影响-结晶聚合物。对用作代表性聚合物的聚丙烯的广泛研究表明,本文所述的流变逻辑性质取决于颗粒组成,尺寸范围和浓度。因此可以根据所选择的颗粒特性来选择固体对液体聚合物的影响。对于大多数涂饰应用而言,固体添加剂的实际好处包括提高生产率,但也可能包括降低成型温度,提高成品聚合物的机械性能,改善添加剂的分散性以及更好地贴合制品。

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