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Simulation and Analysis of Catalytic Distillation for Synthesizing Ethylene Glycol Monobutyl Ether

机译:乙二醇单丁醚合成催化精馏的模拟与分析

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A new application of catalytic distillation (CD) for the synthesis of ethylene glycol monobutyl ether (EGME) from ethylene oxide (EO) and n-butanol was developed recently in our laboratory. The main focus of the present study was to examine the steady state performance of a pilot plant CD column by using a rate-based model. A comparison of three different catalytic packings was performed to investigate the effect of packing characteristics on EO conversion and selectivity toward EGME. The influences of the key operating parameters and heat released by exothermic reaction were investigated. The simulation results obtained in this study indicated that the potential advantages of using CD for synthesizing EGME. A selectivity of 97% toward the desired product EGME could be achieved that was no possible with the traditional processes.
机译:最近在我们实验室中开发了催化蒸馏(CD)从环氧乙烷(EO)和正丁醇合成乙二醇单丁醚(EGME)的新应用。本研究的主要重点是通过使用基于速率的模型来检查中试植物CD色谱柱的稳态性能。进行了三种不同催化填料的比较,以研究填料特性对EO转化率和对EGME的选择性的影响。研究了关键操作参数和放热反应释放的热量的影响。这项研究获得的模拟结果表明,使用CD合成EGME具有潜在的优势。可以实现对所需产物EGME的97%的选择性,这是传统方法无法实现的。

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