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Thermal behaviors of deactivation catalysts for synthesizing 2,3, 5-trimethylhydroquinone

机译:失活催化剂合成2,3,5-三甲基对苯二酚的热行为

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摘要

The thermal behaviors of the deposits on supported noble metal catalysts for synthesizing 2,3, 5-trimethylhydroquinone by DSC were studied. The results show that the supported Pd catalysts have two exothermic peaks at around 312℃ and 435℃ in the DSC thermograms, respectively, while the supported Pt catalysts have one exothermic peak at approximately 345℃. Therefore, it is supposed that the adsorptive states of deposits on supported Pt catalysts and supported Pd catalysts are different, which may be one reason leading to the stability difference between supported Pt catalysts and supported Pd catalysts.
机译:研究了通过DSC合成2,3,5-三甲基对苯二酚的负载型贵金属催化剂上沉积物的热行为。结果表明,在DSC热分析图中,负载型Pd催化剂分别在312℃和435℃有两个放热峰,而负载型Pt催化剂在345℃左右有一个放热峰。因此,可以推测,担载Pt催化剂和担载Pd催化剂上的沉积物的吸附状态不同,这可能是导致担载Pt催化剂和担载Pd催化剂的稳定性差的原因之一。

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