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SUPPORTED GOLD CATALYST THAT IS THERMALLY RESISTANT TO DEACTIVATION PHENOMENA UNDER OPERATING CONDITIONS

机译:在操作条件下对失活现象具有抗性的支持的金催化剂

摘要

The invention relates to a supported gold catalyst that is thermally resistant to deactivation phenomena under operating conditions. More specifically, the invention relates to a catalytic system of formulation Ce02/Au/Ti02, obtained by means of the post-synthesis modification of a gold catalyst supported on a reducible oxide, in this case ΤΊΟ2. The interaction between its three components produces greater catalytic activity in the reaction used as a test (CO oxidation), but, above all, it displays greater stability during treatments in a reaction atmosphere at temperatures of the order of 1223 K. The low thermal stability of gold is currently considered to be one of the main impediments to its commercial use in processes in which it has been shown to be active. In this respect, the catalyst described is presented as a possible solution to these problems, also allowing the use of gold in catalytic applications that require severe thermal conditions.
机译:本发明涉及在操作条件下耐热失活现象的负载型金催化剂。更具体地,本发明涉及通过负载在α-烯烃上的金催化剂的合成后改性获得的配方Ce0 2 / Au / Ti0 2 的催化体系。可还原氧化物,在这种情况下为ΤΊΟ 2 。它的三种成分之间的相互作用在用作测试(CO氧化)的反应中产生了更大的催化活性,但最重要的是,它在1223 K量级的反应气氛中处理过程中显示出更高的稳定性。低热稳定性目前,金被认为是已证明其具有活性的工艺对其商业用途的主要障碍之一。在这方面,所描述的催化剂是解决这些问题的一种可能的方法,也允许在需要严格热条件的催化应用中使用金。

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