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Fabrication of phase-shifting masks employing multilayer films

机译:使用多层膜的相移掩模的制造

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Abstract: The design and fabrication of phase shifting masks using multi-layer films are summarized. Mask blanks consist of fused silica substrates coated with a top chrome layer, an SiO$-2$/ phase layer, and an etch-stop layer. The layer thicknesses are designed to give a $pi@-phase shift at 248 nm (or at 365 nm), and equal and maximal transmission at etched and non-etched regions. The chrome layer is patterned by e-beam resist and is etched by reactive ion etching (RIE) with Cl$-2$/ chemistry. The SiO$-2$/ layer is patterned by another e-beam resist in registration with first chrome pattern and is etched by RIE with CHF$-3$/ chemistry. Two materials were investigated as the etch stop layer, namely Al$-2$/O$-3$/ and HfO$-2$/, with the latter having advantageous properties. It is shown that a 20% processing window is achieved in this type of PSM for a 5 degree phase accuracy as in contrast to quartz etched PSM in which the etched depth and uniformity has to be controlled to within 2.5% for a similar phase accuracy. !12
机译:摘要:总结了使用多层膜的相移掩模的设计和制造。掩模坯料由涂覆有顶部铬层,SiO 2-2 /相层和蚀刻停止层的熔融二氧化硅基底组成。层的厚度设计为在248 nm(或365 nm)处产生ππ相移,并在蚀刻和非蚀刻区域具有相等且最大的透射率。铬层通过电子束抗蚀剂进行图案化,并通过具有Cl $ -2 $ /化学成分的反应离子蚀刻(RIE)进行蚀刻。用另一种电子束抗蚀剂将SiO $ -2 $ /层图案化,使其与第一个铬图案对齐,并通过RIE用CHF $ -3 $ /化学成分进行蚀刻。研究了两种材料作为蚀刻停止层,即Al $ -2 $ / O $ -3 $ /和HfO $ -2 $ /,后者具有有利的特性。结果表明,与石英蚀刻的PSM相比,在这种类型的PSM中,对于5度的相位精度可获得20%的处理窗口,而石英蚀刻的PSM必须将蚀刻深度和均匀度控制在2.5%以内,以实现相似的相位精度。 !12

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