首页> 外文会议>NATO Advanced Study Institute on Electron Crystallography Erice, Sicily 22 May-2 June, 1997 >Modulated Structure Determination of Pb-1212 and Pb-1223 by Electron Crystallographic Image Processing
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Modulated Structure Determination of Pb-1212 and Pb-1223 by Electron Crystallographic Image Processing

机译:电子晶体学分析方法测定Pb-1212和Pb-1223的结构

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摘要

(Pb,Sr,Cu)Sr_2(Ca,Sr0Cu_2O_y(Pb-1212) and (Pb,Sr,Cu)Sr_2(Ca,Sr)_2Cu_3O_y(Pb-1223) are high-T_c superconducting compounds having commensuratwe and incommensurate modulated structure, respectively(1). Modulated structures are characterized ythe periodic deviation of the atomic position and/or the occupation from the average value. The ratio of modulation wavelength of the periodicity of basic structure is aninteger for commensurate meodulated structures, i.e. superstructures, while for incommensurate modulated structures is an irrrational number. Incommensurate modulated structure can be described as a three-dimensional section of a high-dimensional periodic structure(2). In the present paper, it is reported that both commensurate modulated structure of Pb-1212 and incommensurate modulated structure of Pb-1223 were determined by usinmg the two-stage image processing technique (3) which consits of image deconvolution and phase extension.
机译:(Pb,Sr,Cu)Sr_2(Ca,Sr0Cu_2O_y(Pb-1212)和(Pb,Sr,Cu)Sr_2(Ca,Sr)_2Cu_3O_y(Pb-1223)是高T_c超导化合物,具有相称和不相称的调制结构, (1)。调制结构的特征是原子位置和/或原子相对于平均值的周期性偏离;基本结构的周期性的调制波长的比值对于相应的介导结构即上层结构是整数,而对于不等价的结构调制结构是一个无理数,不等调制结构可以描述为高维周期结构的三维截面(2),本文报道了Pb-1212的等价调制结构和不等价的调制结构Pb-1223的结构通过结合图像反卷积和相位扩展的两阶段图像处理技术(3)来确定。

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