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Solid Particle Erosion Protection of Turbine Blades with Thick Nitride and Carbonitride Coatings from Magnetron Sputter Deposition

机译:具有厚氮化物和碳氮化物涂层的涡轮叶片的固体颗粒侵蚀保护磁控溅射沉积

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Solid particle erosion (SPE) damage is a major degradation mechanism for compressor blades of land-based and air gas turbine engines. Not only does erosion reduce the efficiency of the turbines, but it also reduces the service lifetime, thereby reducing the reliability and availability and increasing the overall cost of turbine operation. In desert environments, SPE becomes even more severe and it can lead to the loss of life. To combat erosion thick nitrides (TiN, CrN and ZrN) and carbonitrides (TiSiCN and ZrSiCN) have been deposited using a Plasma Enhanced Magnetron Sputtering (PEMS) technique. The technique combines conventional magnetron sputtering and externally generated plasma from which high current density can be obtained. By using heavy ion bombardment prior to and during deposition to increase the coating adhesion and limit columnar growth, single-layered thick nitrides of TiN, CrN, and ZrN coatings up to 80 micrometers and thick carbonitride coatings of TiSiCN and ZrSiCN up to 30 micrometers have been obtained. Test coupon samples have been subjected to two independent erosion tests. It has been observed that TiSiCN renders the best erosion resistance - nearly 25 times lower than the uncoated stainless steel or Ti-6Al-4V and about 5-10 times lower than all other nitrides. In this paper, we will discuss the deposition technology and the coating microstructure studied using Scanning Electron Microscopy (SEM) with Energy Dispersive X-ray analysis (EDX), Transmission Electron Microscopy (TEM), and X-Ray Diffractometry (XRD). We will present the nano-hardness results from the nanoindentation tests and erosion resistance from the erosion tests. The technology may be applied to protect turbine engine compressor blades, vanes and rotor blades in advanced aircraft and fluid pump impellers as well as piston rings for heavy-duty diesel engines.
机译:固体颗粒腐蚀(SPE)损坏是陆基和空气汽轮机发动机压缩机叶片的主要退化机制。侵蚀不仅可以降低涡轮机的效率,而且还减少了服务寿命,从而降低了可靠性和可用性并增加了涡轮机操作的总成本。在沙漠环境中,SPE变得更加严重,它可能导致生命的丧失。使用等离子体增强的磁控溅射(PEMS)技术,已经沉积了对抗腐蚀厚的氮化氮(TiN,CrN和ZrN)和碳氮(Tisicn和Zrsicn)。该技术结合了传统的磁控溅射和外部产生的等离子体,可以获得高电流密度。通过在沉积之前和在沉积期间使用重离子轰击以增加涂层粘附和极限柱状生长,单层厚氮化物的锡,CrN和ZrN涂层高达80微米和厚的碳氮化物涂层,ZrSICN的厚度高达30微米获得。测试优惠券样本已经受到两个独立的侵蚀测试。已经观察到Tisicn呈现最佳腐蚀性 - 比未涂层不锈钢或Ti-6Al-4V低近25倍,比所有其他氮化物低约5-10倍。在本文中,我们将讨论使用扫描电子显微镜(SEM)与能量分散X射线分析(EDX),透射电子显微镜(TEM)和X射线衍射法(XRD)进行研究的沉积技术和涂层微观结构。我们将提出纳米硬度来自纳米狭窄试验和侵蚀抗性的侵蚀性试验结果。该技术可以应用于保护涡轮发动机压缩机刀片,叶片和转子叶片,以及用于重型柴油发动机的活塞环以及活塞环。

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