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Effect of chemical reagents on ions precipitation of hot spring brine water from Tirtasanita Indonesia

机译:化学试剂对 Tirtasanita Indonesia 温泉盐水离子沉淀的影响

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Brine water is known to contain minerals concentration that can be utilized for many industrial applications but fall short due to the difficulties in extracting it. Commonly known methods to extract the minerals contained in brine water is through the use of chemical reagents to form ion precipitation. In this study, chemical reagents such as Ammonium carbonate ((NH_4)_2CO_3), ammonium hydroxide (NH_4OH), and sodium carbonate (Na_2CO_3) with concentration of 4N was used to precipitate brine water from hot spring of Tirtasanita, Indonesia. In short, the procedure used was in conjunction with previous research, in which the mixing of chemical reagents into brine water with reagent volume ratio varied by 20/1; 5/20; 10/20; 20/20; 20/30; 20/40; 20/50 and 20/60, continued with stirring until precipitation is formed. Filtrate was then separated from the precipitate and characterized with ICP-OES and SEM-EDS, respectively. The preliminary characterization showed that the initial brine water chemical concentration which mainly had 52.8 ppm Ca, 313.9 K, 127.6 ppm Mg, and 1208.9 Na, shift to increase the amount of Ca, K, Mg, and Na after evaporation. The varied volume ratio used for each of the chemical reagents also formed different amount of precipitate, with varying shape and chemical composition. In this experiment the change of each elements in the brine water chemical composition is observed and analyzed. The results of the experiment showed that there are two kinds of salt that can be precipitated from the chemical reagents used, namely, calcium carbonate (CaCO_3) and magnesium chloride (MgCl_2) with the use of (NH_4)_2CO_3 and NH_4OH, respectively. The analysis on precipitated compounds showed that around 90 % of the respective element presents in the resulting salt. The technique and chemical reagents involved are recommended to be used in the synthesis of respective salts from brine water from hot spring due to its simplicity and low cost.
机译:众所周知,盐水含有可用于许多工业应用的矿物质浓度,但由于难以提取而达不到要求。提取盐水中所含矿物质的常用方法是使用化学试剂形成离子沉淀。本研究采用浓度为 4N 的碳酸铵 ((NH_4)_2CO_3)、氢氧化铵 (NH_4OH) 和碳酸钠 (Na_2CO_3) 等化学试剂沉淀印度尼西亚 Tirtasanita 温泉的盐水。简而言之,所使用的程序与以前的研究相结合,其中将化学试剂混合到盐水中,试剂体积比变化 20/1;5/20;10/20;20/20;20/30;20/40;20/50 和 20/60,继续搅拌直至形成沉淀。然后从沉淀物中分离滤液,并分别用 ICP-OES 和 SEM-EDS 表征。初步表征表明,初始盐水化学浓度主要为 52.8 ppm Ca、313.9 K、127.6 ppm Mg 和 1208.9 Na,蒸发后 Ca、K、Mg 和 Na 含量发生变化。用于每种化学试剂的不同体积比也会形成不同数量的沉淀物,具有不同的形状和化学成分。在本实验中,观察和分析了盐水中各元素化学成分的变化。实验结果表明,使用(NH_4)_2CO_3和NH_4OH,分别可以从所使用的化学试剂中沉淀出两种盐,即碳酸钙(CaCO_3)和氯化镁(MgCl_2)。对沉淀化合物的分析表明,所得盐中存在约 90% 的相应元素。由于其简单性和低成本,建议将所涉及的技术和化学试剂用于从温泉盐水中合成相应的盐。

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