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Modification of PHBV-blends with a biodegradable plasticizer

机译:用可生物降解的增塑剂改性PHBV-混合物

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Plastics have become an indispensable part of modern life and due to their outstanding properties, they are used for a wide range of products in a great variety of industrial sectors. However, if plastics are not disposed properly and released into the environment, they become a global problem. Especially the high longevity and durability of plastics lead to undesirable accumulations in terrestrial and aquatic systems. Therefore, both seas and soils become final sinks. Because of that, the prevention of plastic waste in the environment must be highest priority. A solution is needed for those cases in which an entry into the environment cannot be avoided or recycling is not possible. Biodegradable plastics are a possible answer here. Especially, the biopolymer poly-3-hydroxybutyrate-co-3-hydroxyvalerate (PHBV) presents itself as a promising material, although its high brittleness causes some challenges. To address this issue, PHBV was blended with the biopolymer PBAT and a biodegradable plasticizer was added. While analyzing the rheological and mechanical properties, it was observed that with increasing PBAT and plasticizer concentration, both viscosity and Young's modulus decreased while the elongation at break and impact strength increased.
机译:塑料已成为现代生活中不可或缺的一部分,由于其出色的特性,它们用于各种工业领域的广泛产品。但是,如果塑料没有正确处理并释放到环境中,则它们成为一个全球性问题。特别是塑料的高寿命和耐久性导致陆地和水生系统的不良积累。因此,海洋和土壤都变成了最终的水槽。因此,在环境中预防塑料废物必须是最优先的。对于无法避免或回收环境的情况,需要解决这些情况的解决方案是不可能的。可生物降解的塑料在这里是一个可能的答案。特别是,生物聚合物聚-3-羟基丁酸酯-CO-3-羟基戊戊酸酯(PHBV)呈现为有希望的材料,尽管其高脆性导致一些挑战。为了解决这个问题,将pHBV与生物聚合物PBAT混合,并加入可生物降解的增塑剂。在分析流变和机械性能的同时,观察到随着PBAT和增塑剂浓度的增加,粘度和杨氏模量均降低,而断裂处的伸长率和冲击强度增加。

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