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Structural, optical and morphological study on Gd2O3:Eu3+

机译:GD2O3的结构,光学和形态学研究:EU 3 +

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Eu3+ doped Gd2O3 phosphors were synthesized successfully by sol-gel method. The growth of particle was inhibited with the addition of surfactant PEG. The formation of cubic phase Gd2O3 was confirmed from XRD pattern. The reflectance spectra exhibited the absorption peaks corresponding to the dopant and host ions. The excitation spectra showed a broad peak at 248 nm corresponding to ligand to metal charge transfer. A sharp red emission peak at 611 nm indicated the presence of more number of Eu3+ ions in non-inversion symmetry site. The SEM micrograph showed the growth of agglomerated and non-uniform shaped particles with the addition of PEG.
机译:EU 3 + 掺杂GD 2 O 3 通过溶胶 - 凝胶法合成磷光体。 通过添加表面活性剂PEG抑制颗粒的生长。 从XRD图案确认立方相Gd 2 3 的形成。 反射光谱表现出与掺杂剂和宿主离子对应的吸收峰。 激发光谱在与配体相对应为金属电荷转移的248nm处显示宽峰。 在611nm处的急剧红色发射峰表明存在更多数量的非反转对称部位中的EU 3 + / sup>离子。 SEM显微照片显示凝聚和非均匀形颗粒的生长,并加入PEG。

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