Overcharge abuse can trigger thermal runaway when a device is left unattended. Redox shuttles, as economic and efficient electrolyte additives, have been proven to provide reliable and reversible protection for state-of-art Li-ion batteries (LIBs) against overcharge. Here, a functional organic salt, trisaminocyclopropenium perchlorate (TAC·ClO_4), is developed and employed as a redox shuttle for overcharge protection in a Na-ion battery system. This type of novel redox shuttle molecule is reported for the first time. As a unique ionic compound with the smallest aromatic ring structure, TAC·ClO_4 exhibits distinctive attributes of fast diffusion, high solubility, and ultrahigh chemical/electrochemical stability in both redox states. With merely 0.1 M TAC·ClO_4 in electrolyte, Na_3V_2(PO_4)_3 cathode can carry overcharge current even up to 10C or 400% SOC. Na_3V_2(PO_4)_3/hard carbon cells demonstrated strong anti-overcharging ability of 176 cycles at 0.5C rate and 54 cycles at 1C rate with 100% overcharge. Moreover, TAC·ClO_4 addition has little impact on the electrochemical performance of Na-ion batteries, especially on the rate performance and the initial Columbic efficiency. Interestingly, a unique and reversible electrochromic behavior of TAC·ClO_4 electrolyte can promptly provide the device an overcharge alarm under a designed potential to further enhance the safety level.
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