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Influence of the ultrasonic agitation on chemical bath deposition of cadmium sulfide thin films

机译:超声搅拌对硫化镉薄膜化学浴沉积的影响

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Ultrasonic agitation was applied during the chemical bath deposition of CdS thin films. Ultrasonication resulted in a large difference in surface morphology, growth rate, and optical properties of CdS films. There were virtually no colloidal particles adsorbed on the surface. The surface roughness measured by atomic force microscopy was reduced by a factor of two. Band gap energy increased to 2.39 eV from 2.37 eV. X-ray patterns showed that the preferred orientation changed from hexagonal (002)/cubic (111) to hexagonal (101). Optical transmission improved in the longer wavelength range larger than 520 nm. The chemical reaction for CdS formation started at a lower temperature under ultrasonication, and dense films were obtained even when the chemical composition of the aqueous solution deviated far from the optimum conditions
机译:在CDS薄膜的化学浴沉积期间施加超声搅拌。 超声发生导致CDS膜的表面形态,生长速率和光学性质差异很大。 几乎没有吸附在表面上的胶体颗粒。 用原子力显微镜测量的表面粗糙度减少了两倍。 带隙能量从2.37eV增加到2.39eV。 X射线图案表明,优选取向从六边形(002)/立方(111)变为六边形(101)。 光传输在大于520nm的较长波长范围内提高。 Cds形成的化学反应在超声波下的较低温度下,即使水溶液的化学成分远离最佳条件,也可以获得致密的薄膜

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