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Effect of Filter Choice on OH* Chemiluminescence Kinetics at Low and Elevated Pressures

机译:滤波器选择对低升高和升压的OH *化学发光动力学的影响

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Shock-tube experiments have been performed to assess the performance of various optical filters in capturing time-resolved chemiluminescence emission. The purpose was to see if choice of filter bandwidth changed the observed results. Filters included narrow-band ones at ± 10 nm and ± 40 nm and a broadband UG-11 schott filter. The main species of interest was OH*; therefore most of the filters used in this study were centered near 307 nm. Experiments were performed in highly diluted, stoichiometric mixtures of H_2/O_2/Ar and CH_4/O_2/Ar at a wide range of temperatures and pressures behind reflected shock waves in a shock tube. A dual optical setup on both sides of the shock tube was optimized to allow for simultaneous measurements using two different filters. In addition, experimental results were compared with two chemical kinetics models containing OH* chemistry. Good agreement was seen at atmospheric pressures, while the agreement at higher pressures shows that improvements to the model can still be made. For the cases near 1 atm, the results are not filter specific, but some differences are seen at the highest temperatures for the higher-pressure experiments near 16 atm.
机译:已经进行了冲击管实验以评估各种光学滤波器在捕获时间分辨的化学发光发射中的性能。目的是看到过滤器带宽的选择是否改变了观察到的结果。过滤器包括窄带±10nm和±40nm的窄带和宽带UG-11 Schott滤波器。主要感兴趣的是哦*;因此,本研究中使用的大部分过滤器都以307nm靠近。在宽范围的温度和CH_4 / O_2 / AR的高度稀释,化学计量混合物中进行实验,在震动管中的反射冲击波后面的各种温度和压力下进行。优化了冲击管两侧的双光学设置,以允许使用两个不同的过滤器同时测量。此外,将实验结果与含有OH *化学的两种化学动力学模型进行比较。在大气压力下看到良好的一致性,而较高压力的协议表明,仍然可以进行模型的改进。对于近1个ATM的情况,结果不具体滤波,但在16个ATM附近的高压实验的最高温度下看到一些差异。

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