Supramolecular hybrid nanomaterials based on molecularengineering and nanoarchitecturing

摘要

One of the first strategies for the fabrication of soft nanostructured materials was to useself-assembly of chemically programmed molecular building blocks since such a bottom-up,supramolecular approach has shown great potential in developing new cost-effective,functional materials and devices.Tailoring unique nanostructures of organic molecules andthe consequent interpretation of size and shape effects have opened up tremendousopportunities not only to broaden their applications but also to identify new directions forthe design of nanomaterials.In particular,the crystallization-driven assembly of amphiphilicblock copolymer has attracted growing interest in recent years,which provides a novelstrategy for manufacturing functional materials with the well-defined nanostructure.Meanwhile,organic-inorganic hybrid nanomaterials have been investigated to develop theadvanced functional materials through a careful choice of nanoparticles and organiccomponents in a single platform.The introduction of inorganic nanoparticles intoself-assembling organic nanoaggregates offers a powerful route to the preparation of hybridnanomaterials with desired optical,electrical and magnetic functions.