Syntheses and Redox Behaviors of Ruthenium ComplexesHaving Non-innocent Diimine Ligand

摘要

We have been investigating conversion reactions of nitrogen-containing compounds onruthenium complexes bearing two 2,2'-bipyridine (bpy).Amine is one of the well knownreactive nitrogen compounds and it is used as a nitrogen source for syntheses of variousnitrogen-containing compounds.In this work,conversion of amine ligands coordinated tothe ruthenium center accompanied by oxidation of the metal center were studied.