Efficient Photocatalytic Activation of C-H Bonds by Control ofAtom Spatial Distribution on the Layered Silicate

摘要

Owing to the economic and environmental benefits,photocatalytic organic transformationvia C-H activation is a crucially important,while still challenging area.Heterogeneousphotocatalysis has become regarded as a promising alternative strategy in recent years since itcan be used to activate stable alkanes,even in mild conditions,using solar energy directly.1Nonetheless,the lack of efficient photocatalysts for selective production of target organics stillremains the bottleneck for industrialization.