Synthesis of the novel platinum square macrocyclic complex with electron acceptor ligand

摘要

Macrocyclic compounds possess various physical properties such as selective molecular binding and/or reaction field. Since the discovery of the square shaped macrocyclic complex, [Pd(en)(4,4’-bpy)]4(NO3)8 (en = ethylenediamine, 4,4’-bpy = 4,4’-bipyridine) via self- assembly, a variety of square macrocyclic complexes have been reported. However, there are few reports of square complexes with functionalized organic ligands.