Generation of α-Iminyl Radicals from α-Bromo N-Sulfonylimines by Photoredox Catalyst and Application to Various Radical Reactions

摘要

Radical reactions catalyzed by a photoredox catalyst have gained much attention in organic chemistry.1 α-Iminyl radicals are useful candidates as intermediates for the synthesis of imine-containing compounds which have wide application such as the synthesis of the chiral α-tertiary amines.2