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Low-Valent Ti tanium-Mediated Direct C–OH Bond Cleavage of Benzyl Alcohol Derivatives and Its Application to C–C Bond Formation

机译:低价Ti唐尼米介导的苄醇衍生物的直接C-OH键切割及其在C-C键形成中的应用

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摘要

Alcohols, although ubiquitous, have found few practical direct use in radical reactions. Through an esterification or halogenation, alcohols can be employed as the corresponding carbon radical precursors. However, such pre-functionalization steps inevitably elongate synthetic schemes.
机译:饮酒虽然普遍存在,但发现了很少的实际直接用途是激进的反应。通过酯化或卤化,可以使用醇作为相应的碳自由基前体。然而,这种前功能化步骤不可避免地细长的合成方案。

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