In summary, we try to increase the device performance by adding FA~+ to MA~+. As the concentration of MA_(0.8)FA_(0.2) -PbI_(3-y)Cl_y increases, the PCE will increase, and 1.7 M MA_(0.8)FA_(0.2)PbI_(3-y)Cl_y gives the best photovoltaic performance. To get high performance lead-reduced PSCs, we combine Ba~(2+) substitution of Pb~(2+) with 1.7 M MA_(0.8)FA_(0.2) -PbI_(3-y)Cl_y. When 5.0 mol% Ba~(2+) is doped, the best MA_(0.8)FA_(0.2)Ba_(0.05)Pb_(0.95)I_(3-y)Cl_y device gives V_(oc) of 1.06 V, J_(sc) of 22.3 mA/cm~2, FF of 70.4% and PCE of 16.6%.
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机译:总之,我们尝试通过将FA〜+添加到MA〜+来提高设备性能。由于MA_(0.8)FA_(0.2)-PBI_(3-Y)CL_Y的浓度增加,PCE将增加,1.7米MA_(0.8)FA_(0.2)PBI_(3-Y)CL_Y提供了最佳的光伏性能。为了获得高性能铅减少的PSC,我们将PB〜(2+)的Ba〜(2+)替换为1.7 m ma_(0.8)fa_(0.2)-pbi_(3-y)cl_y。当5.0 mol%ba〜(2+)被掺杂时,最好的MA_(0.8)FA_(0.2)BA_(0.05)PB_(0.95)I_(3-Y)CL_Y设备给出了1.06 V,J_的V_(OC)( SC)22.3 mA / cm〜2,FF为70.4%,PCE为16.6%。
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