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Study on the optical properties of polyvinyl alcohol doped sodium fluoride polymer electrolyte films

机译:聚乙烯醇掺杂氟化钠聚合物电解质膜的光学性质研究

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In the present work, pure polyvinyl alcohol (PVA) and PVA doped with sodium fluoride (NaF) polymer electrolyte films with different weight percent ratios were prepared by solution casting method. The effect of NaF concentration on the optical properties of (PVA-NaF) films has been investigated using UV-Vis Spectrophotometer in the wavelength range (200-800 nm). The optical constants like absorption spectra, transmission spectra, refractive index, extinction coefficient, real and imaginary parts of the dielectric constant and optical band gaps are investigated. It was found that the optical energy band gap is decreased upon the increase in NaF salt concentration which is contrary to the variation of conductance. The experimental results show that the optical constants showed clear changes with increasing the doping concentrations.
机译:通过溶液铸造方法制备掺杂含有氟化钠(NAF)聚合物电解质膜的纯聚乙烯醇(PVA)和PVA。 使用波长范围(200-800nm)的UV-Vis分光光度计研究了NAF浓度对(PVA-NAF)膜的光学性质的影响。 研究了吸收光谱,透射光谱,折射率,消光系数,介电常数和光带间隙的透射谱,折射率,消光系数,实体和虚部的光学常数。 结果发现光能带隙在与电导变化相反的Naf盐浓度的增加时降低。 实验结果表明,光学常数显示出随着掺杂浓度的增加而变化。

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