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Influence the Dopant Concentration on the Photocatalytic Activity: Dy~(3+), Eu~(3+) doped TiO_2

机译:影响光催化活性的掺杂剂浓度:Dy〜(3+),Eu〜(3+)掺杂TiO_2

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Titanium dioxide (TiO_2) nanoparticles were synthesis by means of hydro thermal process from metatitanic acid. The impacts reaction temperature, stirring process and aging time on the morphology, the transfer of nanoparticles particles were characterized. The morphology of the nanoparticles was described in detail with scanning electron microscopy. In the dynamic of hydro thermal method, stirring can cut down the reaction time of change from particles to nanoparticles. As can be seen from the XRD patterns, the diffraction peaks get broadened as the Eu~(3+) focus is increased, proposing an orderly abatement in the grain size. The Crystallite size was calculated for pure, Dy~(3+) and Eu~(3+) doped TiO_2 from diffraction plane by Sherrer's formula and it was found that 13 nm to 18 nm. From SEM images the majorities of TiO_2 particles are oblate spheroid or spheroid and look looser, and some macropores could be seen on a few particles.
机译:通过来自氰酸酸的水热法合成二氧化钛(TiO_2)纳米颗粒。影响反应温度,搅拌过程和老化时间对形态的形态,表征纳米颗粒的转移。用扫描电子显微镜详细描述了纳米颗粒的形态。在水力热法的动态中,搅拌可以切下从颗粒到纳米颗粒的变化的反应时间。从XRD图案中可以看出,随着EU〜(3+)焦点的衍射峰被增加,提高了晶粒尺寸的有序减少。通过Sherrer公式计算纯,Dy〜(3+)和Eu〜(3+)掺杂TiO_2的微晶尺寸,发现13nm至18nm。来自SEM图像的多数TiO_2颗粒是扁圆形的球形或球状,看起来松动,并且可以在几种颗粒上看到一些大孔。

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