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Studies on Optical Properties of CdS/ZnO Quantum Dots Prepared by Sol-Gel Method

机译:溶胶 - 凝胶法制备CDS / ZnO量子点的光学性质研究

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CdS/ZnO quantum dots (QDs) were prepared at a temperature of 293 K by the sol-gel method with Triethanolamine (TEA) as a capping agent. The effect of CdS/ZnO mixture ratio of 1:9, 1:1 and 9:1 on the optical absorption and fluorescence spectra were investigated by UV-Vis and Fluorescence spectroscopy. By increasing ZnO composition, a blue-shift of absorption edge and emission spectra were observed. The band gap for 1:9, 1:1 and 9:1 were found to be 4.13, 3.93 and 3.11 eV, respectively. The morphology of the CdS/ZnO QDs for each mixing ratio was obtained by transmission electron microscope (TEM). The size of the QDs was found to be in the range of 5-10 nm with some agglomerated particles.
机译:Cds / ZnO量子点(QDS)通过用三乙醇胺(TEA)作为封端剂的溶胶 - 凝胶法在293k的温度下制备。通过UV-VI和荧光光谱研究了CDS / ZnO混合比为1:9,1:1和9:1的效果,对光学吸收和荧光光谱进行了研究。通过增加ZnO组合物,观察到吸收边缘和发射光谱的蓝色偏移。发现1:9,1:1和9:1的带隙分别为4.13,3.93和3.11eV。通过透射电子显微镜(TEM)获得每个混合比的CDS / ZnO QD的形态。发现QD的大小在5-10nm的范围内,具有一些附聚颗粒。

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