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Synthesis and Dispersion of Organic Pigments by Amptiiphilic Hyperbranched Polyesteramides Dispersant

机译:氨基硅酸盐超支化聚酯酰胺分散剂的合成与分散

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The amphiphilic hyperbranched polyesteramides(AHPAs)consisting of hydrophobic hyperbranched polyether cores and hydrophilic poly(ethyleneglycol)arms with urethane bonds in the molecular structure were synthesized by solution polymerization in chloroform using hexamethylene diisocyanate(HMDI)as a coupling agent.And their chemical structures were confirmed by FT-IR and and 13C NMR.Further,the AHPAs were applied to disperse organic pigments and their dispersibilities were investigated.The results showed that AHPAs had good dispersing effect on organic pigments.When the dosage of AHPA was 12%(on the weight of pigment),the dispersing effect of AHPA on phthalocyanine green was the best with the lowest relative settlement rate,viscosity and particle size.The dispersibilities of AHPA on organic pigments were phthalocyanine green > benzidine yellow G > pigment red F5R.AHPAs have the characteristics of high solubility,low viscosity,good rheological properties and no pollution and would be the ideal materials for using as the pigment dispersants.
机译:所述两亲性超支化聚酯(AHPAs)由疏水性多支化聚醚芯和亲水性聚(乙二醇)与在分子结构中尿烷键臂的通过溶液聚合中使用氯仿二异氰酸酯(HMDI),其为耦合agent.And它们的化学结构,合成通过FT-IR和13C和NMR.Further确认,则AHPAs分别适用于分散有机颜料和它们的分散度的影响。结果表明,AHPAs对有机pigments.When AHPA的用量为12%的良好的分散效果(在重量颜料的),AHPA对酞菁绿的分散效果最好具有最低相对沉降速率,粘度和颗粒size.The上的有机颜料的AHPA均分散度酞菁绿>联苯胺黄G>颜料红F5R.AHPAs具有高溶解度,低粘度,良好的流变性能和无污染的特性和将是ID EAL材料用于使用作为颜料分散剂。

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