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Chitosan nanoparticles on a natural zeolite as an efficient adsorbent for Congo red

机译:壳聚糖纳米粒子在天然沸石上作为刚果红色的有效吸附剂

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Congo red is a toxic synthetic dye that cannot be readily degraded by conventional methods,thus posing a risk to the environment.The increased use of this dye is mainly due to developments in the textile industry.A possible way to reduce the Congo-red waste is by performing the adsorption processes;therefore,in this study,we used a natural zeolite from Bayah and modified it using chitosan nanoparticles(Na-zeolite@chitosan)to increase its adsorption capacity.The obtained Na-zeolite@chitosan material,which was able to efficiently adsorb Congo red,was further characterized by ultraviolet-visible(UV-Vis)and Fourier-transform infrared(FTIR)spectroscopy as well as by transmission electron microscopy(TEM).A maximum of 98.019% of the Congo red was adsorbed at a concentration of 800 ppm and a pH of 5 for 60 min(the adsorption capacity was 0.00428 mmol/g).Our results exhibit that Congo red adsorption on Na-zeolite@chitosan follows the Freundlich adsorption isotherm and can be described using a pseudo-second-order kinetic model.
机译:刚果红色是一种有毒合成染料,不能通过常规方法易于降解,从而对环境产生风险。这种染料的使用增加主要是由于纺织业的发展。减少刚果红色废物的可能方法是通过进行吸附过程;因此,在本研究中,我们使用从Bayah天然沸石和使用壳聚糖纳米颗粒(钠沸石@壳聚糖),以增加其吸附capacity.The获得的Na沸石改性它@壳聚糖材料,这是能够有效地吸附刚果红色,通过紫外 - 可见(UV-VI)和傅立叶 - 变换红外(FTIR)光谱以及通过透射电子显微镜(TEM).a最多98.019%的刚果红色被吸附在800 ppm的浓度和60分钟,pH为5(吸附容量为0.00428毫摩尔/克)。我们的结果表现出刚果红上吸附的Na沸石@壳聚糖遵循Freundlich吸附等温线,并且可以使用AP来描述Seudo-二阶动力学模型。

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