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Anhydrous Weight Loss Prediction of Meranti Sawdust during Torrefaction using Rousset Model

机译:使用Rousset模型在烘焙过程中Meranti Sawdust的无水重量损失预测

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In torrefaction, the mass loss distribution is evaluated in terms of anhydrous weight loss (AWL). Since temperature gives significant effects on AWL and the behaviour of biomass is highly associated with the AWL, therefore a suitable model for estimating the reaction kinetics is necessary for describing the thermal degradation and predicting the AWL in order to improve its process. In this study, the kinetic parameters of Meranti sawdust are estimated by applying three-parallel reaction models namely the Rousset Model for torrefaction of Meranti sawdust at temperatures of 240°C, 270°C and 300°C. All kinetic parameters are estimated according to the degradation of biomass constituents which are lignin, cellulose and hemicellulose by following the Arrhenius Law. The result shows that AWL estimation using the kinetic parameters predicted from the Rousset model is in good agreement with the experimental result as the R~2 value obtained is 0.99. It shows that the Rousset Model successfully described the degradation of lignin, cellulose and hemicellulose as well as the formation of char, volatile, tar and intermediate compound. Therefore it can be concluded that the Rousset Model is applicable to represent the torrefaction behaviour.
机译:在烘焙中,根据无水重量损失(AWL)评估质量损失分布。由于温度对AWL产生了显着的影响,并且生物质的行为与AWL高度相关,因此用于估计反应动力学的合适模型对于描述热劣化和预测AWL以改善其工艺是必要的。在该研究中,通过施加三个平行的反应模型估计Meranti Sawdust的动力学参数即,在240℃,270℃和300℃的温度下使用Meranti Sawdust的粘滞模型。根据以arrhenius法律,根据木质素,纤维素和半纤维素的生物质成分的降解估计所有动力学参数。结果表明,使用从Rousset模型预测的动力学参数的AWL估计与实验结果非常一致,因为所获得的R〜2值为0.99。它表明,围栏模型成功地描述了木质素,纤维素和半纤维素的降解以及炭,挥发,焦油和中间体的形成。因此,可以得出结论,围栏模型适用于代表烘焙行为。

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