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Synthesis, structural and morphological studies of Sr~(2+) and Gd~(3+) co-doped Ceria electrolyte system for LT-SOFC

机译:用于LT-SOFC的Sr〜(2+)和Gd〜(3+)共掺杂二氧化铈电解质系统的合成,结构和形态学研究

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This paper reports the effect of Sr~(2+) addition on the structural, microstructural properties of Ce_(0.8)Gd_(0.2)O_(2-δ)(GDC) electrolyte for low temperature solid oxide fuel cell application. The Sr~(2+) (0, 0.5, 1 and 2 mol %) doped GDC solid electrolytes have been prepared by solid state method. The sintered densities of the samples are around 95%. XRD study reveals the cubic fluorite structure. The microstructure of the samples resulted into grain sizes in the range of 4.3 to 0.868 μm. Raman spectra also confirms the presence of GDC single phase.
机译:本文报告了Sr〜(2+)添加对低温固体氧化物燃料电池应用的Ce_(0.8)Gd_(0.2)O_(2-δ)(GDC)电解质的结构,微观结构性能的影响。通过固态方法制备Sr〜(2+)(0,0.5,1和2摩尔%)掺杂GDC固体电解质。样品的烧结密度约为95%。 XRD研究揭示了立方萤石结构。样品的微观结构导致晶粒尺寸在4.3至0.868μm的范围内。拉曼光谱还证实了GDC单相的存在。

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