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Modifying Proppant Surface with Nano-Roughness Coating to Enhance Fracture Conductivity

机译:用纳米粗糙度涂层改性支撑剂表面以增强裂缝电导率

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Nano-Roughness coating reduces the fluid/solid interaction leading to super-hydrophobicity or the Lotus effect.The objective of this study is to determine how this phenomenon can be applied in petroleum production system to enhance fluid flow in propped fractures using nano-roughness coating on the surface of proppants.The permeability and the wettability of coated proppant packs are compared with non-coated packs to determine the reduction in friction or enhancement in fracture conductivity.The simulation of flow in a proppant pack is done using sand packs of different permeabilities.The base case for the work is established using sandstone samples with various permeabilities.The sandstone samples include Gray-Berea with uncoated absolute permeability of 86 mD,Buff Berea with uncoated absolute permeability of 374 mD,Bentheimer sandstone with uncoated absolute permeability of 277 mD and Leopard sandstone with the uncoated absolute permeability of 803 mD.The sand packs used are 20/40 mesh with uncoated absolute permeability of 31 D,40/60 mesh with uncoated absolute permeability of 22 D and 50/70 mesh with uncoated absolute permeability of 21 D.After measuring the absolute permeability,wettability(using contact angle method)and relative permeability,all the samples were coated and the properties were measured again.The results show that the modification enhances fluid flow through pores.The surfaces for all the samples were altered from a hydrophilic to a hydrophobic surface.The contact angle between the fluid and samples was observed to be almost 90° with water and >60° for oil,after modification.This confirms modification of samples to partial-wetting state.An increase in absolute permeability is observed from 14.54% for Gray-Berea to 184% for Leopard sandstone.The increase in absolute permeability for sand packs is observed from,23% for 20/40 mesh sand,to 5.28% for 50/70 mesh sand.It was observed that modification is more efficient for a sample with a higher permeability,but further studies are in process to relate the permeability enhancement to total surface area.Since the production rate of tight sandstone and shale reservoirs is low,especially in liquid-rich reservoirs and significant amount of water is injected for reservoir stimulation,enhancement in fracture conductivity resulting from proppant surface modification can have a meaningful impact on the recovery of these reservoirs.This study uses experimental techniques to show the effectiveness of nano-roughness coating on the reduction of friction which can lead to enhancement in fracture conductivity.
机译:纳米粗糙度涂层可降低流体/固体相互作用,导致超级疏水性或莲花效应。本研究的目的是确定这种现象如何应用于石油生产系统中,以增强使用纳米粗糙涂层的裂缝中的流体流动在支撑剂的表面上。将涂覆支撑剂包装的渗透性和润湿性与非涂层包装进行比较,以确定裂缝电导率的摩擦或增强的降低。使用不同渗透的砂包进行支撑剂包装的流动模拟。使用具有各种渗透率的砂岩样品建立了工作的基础案例。砂岩样品包括灰白色的无涂层绝对渗透率为86md,Buff Berea,具有374 md的未涂覆的绝对渗透性,底线砂岩具有277 md的无涂层绝对渗透性。和豹纹砂岩,具有803 md的未涂层绝对渗透率。使用的砂包是20/40 Sh具有31d,40/60目的,具有22d和50/70目的的未涂覆的绝对渗透性,具有21 d的未涂覆的绝对渗透率,可在21 d的绝对渗透率下测量绝对渗透性,润湿性(使用接触角法)和相对渗透率,涂覆所有样品并再次测量该性质。结果表明,改性可通过孔改变流体流动。所有样品的表面从亲水到疏水表面改变。观察到流体和样品之间的接触角在水下后,用水和> 60°近90°,达到近90°。该方法证实了对部分润湿状态的样品的改性。绝对渗透性的增加从14.54%的灰白菜观察到Leopard砂岩184%。观察到砂包的绝对渗透性的增加,对于20/40目沙的23%,对于50/70目沙的5.28%。观察到改性更有效地具有更高的渗透物的样品但进一步的研究是在过程中涉及完全表面积的渗透性提高。纯砂岩和页岩储存器的生产率低,特别是在富含液体的储层中,注入大量水库刺激,增强采用支撑剂表面改性产生的断裂电导可能对这些储层的回收产生有意义的影响。本研究采用实验技术来显示纳米粗糙度涂层对摩擦的减少的有效性,这可以导致裂缝导电性增强。

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