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Determination of iron ore mineralogy using Fourier transform infrared spectroscopy and machine learning

机译:傅立叶变换红外光谱法测定铁矿石矿物学的测定

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Fourier transform infrared (FTIR) spectroscopy and other near infrared (NIR) tools have been used in the bauxite industry for many years. Infrared spectroscopy exploits the differences in chemical composition and lattice structure to produce a characteristic response. Spectral devices, such as those from ASD Inc and the HyLogger~(TM), provide qualitative mineralogical data targeted towards hydrated minerals detected in the near and short wave infrared region. The FTIR spectrum extends into the mid and thermal infrared range and can therefore respond to the presence of silicates and oxides, in addition to hydrates and carbonates.The key to successful utilisation of infrared spectra, however, is the interpretation methodology. In this study, FTIR spectra were calibrated against quantitative X-ray diffraction data for the determination of the mineralogy of iron ore. A full pattern profiling machine learning technique was utilised for the calibration, and the assessment of the regressions determined from an independent validation set. The abundance of key minerals - hematite, goethite, kaolinite and quartz - were determined and the results correlated against X-ray fluorescence assays and loss on ignition data. The results of the study indicate that spectral techniques using a full-pattern profiling machine learning approach and artificial neural networks can be used successfully to obtain objective and quantitative mineralogical data to support field observations and analytical results for iron ore resource modelling. A comparison of this technique to the cost, quality and timeliness of other quantitative mineralogy tools is also made.
机译:傅里叶变换红外线(FTIR)光谱和其他近红外(NIR)工具已在铝土矿行业使用多年。红外光谱剥削化学成分和晶格结构的差异以产生特征反应。诸如来自ASD INC和Hylogger〜(TM)的光谱装置提供针对在近波红外区域中检测到的水合矿物的定性矿物学数据。 FTIR光谱延伸到中间红外线范围内,因此可以响应水合物和碳酸盐之外的硅酸盐和氧化物的存在。然而,成功利用红外光谱的关键是解释方法。在该研究中,抗FTIR光谱与定量X射线衍射数据进行校准,以确定铁矿石的矿物学。用于校准的全模式分析机学习技术,并评估从独立验证集确定的回归。确定核心矿物质,赤铁矿,甲酸酯,高岭石和石英 - 均确定,结果与X射线荧光测定和点火数据损失相关。研究结果表明,使用全模式分析机学习方法和人工神经网络的光谱技术可以成功地用于获得目标和定量矿物学数据,以支持用于铁矿石资源建模的现场观察和分析结果。该技术对其他定量矿物学工具的成本,质量和及时性进行了比较。

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