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Decolourization of methyl orange using iron- immobilize MKSF in UV assisted Fenton-like reaction

机译:使用铁辅助UV辅助FENTON样反应的铁橙的甲基橙脱色

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In this work, montmorillonite KSF clay was used to immobilize iron species as a potential heterogeneous UV assisted Fenton-like reaction. Iron-immobilized MKSF (Fe-MKSF) was synthesized via hydrothermal method in an autoclave. Fe-MKSF was tested on methyl orange (MO) removal by adsorption (5%) and hydrogen peroxide (H_2O_2) activation (63%) and these prominent margins proved Fe-MKSF performance was attributed by UV assisted Fenton-like reaction. Fe-MKSF show superior performance with 63% color removal within 180 mins reaction in comparison to iron oxide and pristine MKSF. The Fe-MKSF increased in the surface area from 91.1 to 101.9 m~2/g and pore volume from 0.13 to 0.45 cm~3/g compared to pristine MKSF. The SEM images of Fe-MKSF show iron aggregates indicating successful immobilizing process and the elemental weight percent of iron which increase from 6.12% to 55.38% in Fe-MKSF. These findings prove Fe-MKSF as a promising alternative catalyst in dye contaminated wastewater treatment.
机译:在这项工作中,Montmorillonite KSF粘土用于将铁物种固定为潜在的非均相UV辅助FENTON样反应。通过在高压釜中通过水热法合成铁固定化的MKSF(Fe-MKSF)。通过吸附(5%)和过氧化氢(H_2O_2)活化(63%)和这些突出的边缘证明Fe-MKSF性能归因于UV辅助Fenton反应归因于甲基橙(5%)和过氧化氢(H_2O_2)和这些突出的余量。 Fe-MKSF显示出优异的性能,与氧化铁和原始MKSF相比,在180分钟的反应中,在180分钟内去除63%的颜色。与原始MKSF相比,Fe-MKSF在91.1至101.9m〜2 / g的表面积增加到101.9m〜2 / g,孔体积为0.13至0.45cm〜3 / g。 Fe-MKSF的SEM图像展示了铁聚集体,表明成功的固定过程和铁的元素重量百分比从Fe-MKSF中的6.12%增加到55.38%。这些发现证明了Fe-MKSF作为染料污染废水处理中有前途的替代催化剂。

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