Palladium Catalysts Based on Mesoporous Organic Materials in Semihydrogenation of Alkynes

机译：基于艾基溶解的钯有机材料的钯催化剂

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Catalyst based on palladium nanoparticles and poly(propyleneimine) (PPI) dendrimers immobilized on mesoporous phenol-formaldehyde support was synthesized. Catalytic characteristics were evaluated in the hydrogenation of 1-octyne, 4-octyne, and 1-hexyne. High selectivity for alkenes (up to 99%) was achieved. Synthesized hybrid catalyst can be recycled without a loss of activity and additional regeneration.

机译：合成基于钯纳米颗粒的催化剂和固定在中孔酚醛甲醛载体上的钯纳米颗粒和聚（加丙基亚胺）（PPI）树枝状体。在1-octyne，4-octyne和1-Hexyne的氢化中评价催化特性。实现了烯烃的高选择性（最高99％）。合成的杂化催化剂可以再循环而不会丧失活性和额外的再生。

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《International Symposium on Macromolecular Complexes》|2016年|1 CD-ROM|共7页
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Maksim P. Boronoev; Anna V. Zolotukhina; Victoria I. Ignatyeva;
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中图分类合成树脂与塑料工业;
关键词
catalysis; dendrimers; hydrogenation; mesoporous polymers; nanoparticle palladium;

机译：催化;树枝状大分子;氢化;中孔聚合物;纳米粒子钯;

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1. Palladium Catalysts Based on Mesoporous Organic Materials in Semihydrogenation of Alkynes [J] . Maksim P. Boronoev, Anna V. Zolotukhina, Victoria I. Ignatyeva, Macromolecular symposia . 2016,第Null期

机译：介孔有机材料在炔烃半加氢中的钯催化剂
2. Excellent Selectivity with High Conversion in the Semihydrogenation of Alkynes using Palladium-Based Bimetallic Catalysts [J] . ChemCatChem . 2017,第21期

机译：利用钯的双金属催化剂在炔烃的半氢化高转化方面具有优异的选择性
3. Discovery of Highly Selective Alkyne Semihydrogenation Catalysts Based on First-Row Transition-Metallated Porous Organic Polymers [J] . Kristine K. Tanabe, Magali S. Ferrandon, Nathan A. Siladke Angewandte Chemie . 2014,第45期

机译：基于第一行过渡金属化多孔有机聚合物的高选择性炔烃半加氢催化剂的发现
4. Palladium Catalysts Based on Mesoporous Organic Materials in Semihydrogenation of Alkynes [C] . Maksim P. Boronoev, Anna V. Zolotukhina, Victoria I. Ignatyeva International Symposium on Macromolecular Complexes . 2016

机译：基于艾基溶解的钯有机材料的钯催化剂
5. The investigation of photocatalysts and iron based materials in the oxidation and adsorption of toxic organic and chromium materials. [D] . Jiang, Wenjun. 2013

机译：研究光催化剂和铁基材料在有毒有机和铬材料的氧化和吸附中的作用。
6. Visible light functioning photocatalyst based on Al2O3 doped Mn3O4 nanomaterial for the degradation of organic toxin [O] . Safi Asim Bin Asif, Sher Bahadar Khan, Abdullah M Asiri 2015

机译：基于Al2O3掺杂的Mn3O4纳米材料的可见光功能光催化剂降解有机毒素
7. Tuning the Selectivity of Palladium Catalysts for Hydroformylation and Semihydrogenation of Alkynes: Experimental and Mechanistic Studies [O] . -1

机译：调节钯催化剂的钯催化剂和半萘氢化的选择性：实验和机械研究
8. Novel Mesoporous Uranium-Oxide Based Catalysts for Removal of VolatileHydrocarbons and Chloro-Organic Compounds: Synthesis and Reactivity Studies [R] . Konduru, M. V. 2001

机译：用于去除挥发性烃和氯有机化合物的新型介孔铀氧化物催化剂：合成和反应性研究

Palladium Catalysts Based on Mesoporous Organic Materials in Semihydrogenation of Alkynes

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