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Effect of annealing in hydrogen atmosphere on ZnO films for field emission display

机译:氢气氛退火对ZnO薄膜的辐射膜发射显示

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Surface morphology, crystallinity, conductivity and optical transmittance of ZnO films can be modified by annealing process. Hydrogen is one of the popular annealing gases as well as nitrogen, argon, oxygen and air which are commonly used for thin film cleaning or the removal of native oxide. In general, annealing is done at high temperatures (>600degC) to improve the film properties. From a view point of environment, however, lower annealing temperature is preferable. In this work, low annealing process was challenged to understand the effect of annealing temperature on properties of ZnO thin films and nanostructured film grown on glass substrates for transparent field emission device applications. The annealing temperature employed was 100, 200 and 450° C at 100 seem hydrogen flow rate. ZnO thin films were deposited by RF magnetron sputtering. The ZnO thin films were characterized by X-ray diffraction analysis (XRD), Atomic Force Microscopy (AFM), UV-VIS and Raman spectroscopy. The sheet resistances reduced about 15 kohm/sq at low annealing temperature. By contrast, the optical transmittance did not show any significant changes after annealing. The FE current density increased after the ZnO nanostructures film was annealed in 100'C. The results obtained could motivate a surface treatment for flexible ZnO thin film since the substrate is always suffered by heat.
机译:通过退火过程可以改变表面形态,结晶度,导电性和光学透射率。氢是流行的退火气体之一以及氮,氩气,氧气和空气,其通常用于薄膜清洁或去除天然氧化物。通常,退火在高温(> 600degc)处完成以改善膜性能。然而,从视图的环境中,更低的退火温度是优选的。在这项工作中,低退火过程受到挑战,以了解退火温度对透明场发射装置应用的玻璃基板上生长的ZnO薄膜和纳米结构膜性能的影响。采用的退火温度为100,200和450℃,100μmIc致氢流速。通过RF磁控溅射沉积ZnO薄膜。 ZnO薄膜的特征在于X射线衍射分析(XRD),原子力显微镜(AFM),UV-Vis和拉曼光谱。薄层电阻在低退火温度下减少约15 kohm / sq。相比之下,光透射率在退火后没有显示出任何显着的变化。在100'C中退火后,Fe电流密度增加。所得到的结果可以促进柔性ZnO薄膜的表面处理,因为基材总是通过热量遭受。

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