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Optical Properties Analysis of Ta-doped TiO_2 Thin Films on LaAlO_3 Substrates

机译:拉马_3基材上TA掺杂TiO_2薄膜的光学性质分析

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We study optical properties of Ta-doped TiO_2 thin film on LaAlO_3 substrate using spectroscopy ellipsometry (SE) analysis at energy range of 0.5 - 6.5 eV. Room temperature SE data for Ψ (amplitude ratio) and Δ (phase difference) between p- and s- polarized light waves are taken with multiple incident angles at several spots on the samples. Here, absorption coefficient has been extracted from SE measurements at photon incident angle of 70° for different Ta concentration (0.01, 0.4, and 5 at. %). Multilayer modelling is performed which takes into account reflections at each interface through Fresnel coefficients to obtain reasonably well the fitting of Ψ and Δ data simultaneously. As the results, we estimate that film thickness increases by increasing Ta concentration accompanied by the formation of a new electronic structure. By increasing Ta impurities, the blueshift of absorption coefficient (α) peaks is observable. This result indicates that TiO_2 thin film becomes optically resistive by introducing Ta doping. Schematic model of interband transition inTiO_2:Ta will be proposed base on obtained optical properties. This study enables us to predict the role of Ta doping on the electronic and optical band structures of TiO_2 thin film.
机译:我们在Laalo_3基板上使用光谱椭圆形(SE)分析在0.5-6.5eV的能量范围内研究TA掺杂TiO_2薄膜的光学性质。在样品上的几个斑点处,在P和S偏振光波之间的ψ(幅度比)和Δ(相位差)的室温SE数据在样品上的几个斑点上拍摄。这里,对于不同的TA浓度(0.01,0.4和5.%),从70°的光子入射角的Se测量中提取了吸收系数。执行多层建模,其通过菲涅耳系数考虑每个接口的反射,以同时获得合理的ψ和δ数据的拟合。作为结果,我们估计膜厚度通过增加通过形成新的电子结构而伴随的TA浓度而增加。通过增加Ta杂质,可以观察到吸收系数(α)峰的蓝色。该结果表明,通过引入Ta掺杂,TiO_2薄膜变得光学电阻。基于带式转换INTIO_2的示意图:TA将在获得的光学性质上提出基础。该研究使我们能够预测TA掺杂对TiO_2薄膜的电子和光学带结构的作用。

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