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Synthesis and characterization of the microcellular injection molded PA6/flax and the PA6/graphene nanoconiposites

机译:微孔注塑成型PA6 /亚麻和PA6 /石墨烯纳米阳乳乳清的合成与表征

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Polymer composites combine two materials together to produce a unique property which is not inherent to the individual materials. The most important reason to use composites is the enhancement of the mechanical properties. However, there are several applications that can be used by composites, such as the heavy metal adsorption of waste water by flax. This study has investigated the effects of flax (1, 3, 5 wt%) and graphene loading (0.5, 1, 3 wt%) on the tensile strength, thermal, and heavy metal adsorption properties of the microcellular injection molded PA6 composites. The fillers used, flax and graphene, were micro and nano materials in size, respectively. The results showed that the dispersion with 0.5 wt% of graphene loading, as seen in the TEM pictures, had the best dispersion for the PA6/graphene nanocomposites. This amount of graphene also had the best tensile strength in three different loadings (0.5, 1.0, 3.0 wt%). Tensile strength was related to the filler dispersion in the matrix. Good dispersion resulted in good tensile strength, and the elongation decreased by increasing the flax loading. The 5 wt% flax loading and 3 wt% graphene loading of the composites showed the largest storage modulus for the PA6composites. The 1 wt% of the flax loading showed the highest degradation temperature for the PA6/flax micro-composites, and the 3 wt% for the PA6/graphene nanocomposites. The cell size decreased and the cell density increased with the addition of graphene to the PA6 composites. Heavy metal of the Cr(IV)adsorption test showed that the PA6/0P nanocomposites had a better adsorption than that of the PA6/flax composites.
机译:聚合物复合材料将两种物质组合在一起以产生非固有的独特性质,该性质不是各种材料固有的。使用复合材料的最重要原因是提高机械性能。然而,有几种可以通过复合材料使用的应用,例如亚麻通过废水的重金属吸附。该研究研究了亚麻(1,3,5wt%)和石墨烯负载(0.5,1,3重量%)对微孔注射成型PA6复合材料的拉伸强度,热和重金属吸附性能的影响。使用的填料,亚麻和石墨烯,分别为微型和纳米材料。结果表明,在TEM图片中看到的0.5wt%的石墨烯负载分散,对PA6 /石墨烯纳米复合材料具有最佳的分散体。该量的石墨烯也具有三种不同载荷(0.5,1.0,3.0wt%)的最佳拉伸强度。拉伸强度与基质中的填充分散体有关。良好的分散体导致良好的拉伸强度,并且通过增加亚麻负载来降低伸长率。复合材料的5wt%的亚麻加载和3wt%石墨烯负载显示Pa 6孔料的最大储存量模。 1wt%的亚麻负载显示PA6 /亚麻微复合材料的最高降解温度,以及PA6 /石墨烯纳米复合材料的3wt%。细胞尺寸降低,并且通过将石墨烯加入PA6复合材料的增加而增加,细胞密度增加。 Cr(iv)吸附试验的重金属显示PA6 / 0p纳米复合材料具有比PA6 /亚麻复合材料的吸附更好。

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