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Nonequilibrium Quantum Dynamics of Biomolecular Excitons

机译:非分子激子的量子动态

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摘要

We investigate the effect of equilibrium and nonequilibrium localized vibrations on the excitation energy transfer efficiency of the Fenna-Matthews-Olson complex. By means of numerically exact real-time path-integral simulations of the transfer dynamics we find that equilibrium vibrations do not enhance coherence times. On the other hand, nonequilibrium vibrations induce prolonged coherence times and increased transfer efficiency. By quantifying the transfer dynamics in terms of a non-Markovianity measure based on the time evolution of the trace distance of two quantum states we find, in all cases, a monotonic decrease of the trace distance with increasing time which implies that the exciton transfer follows a Markovian dynamics.
机译:我们研究了平衡和非醌局部振动对FENNA-MATTHEWS-OLSON复合物的激励能量转移效率的影响。借助于传输动态的数值精确的实时路径积分模拟,我们发现平衡振动不会增强相干时间。另一方面,非平衡振动诱导延长的相干时间并提高转移效率。通过基于两种量子状态的痕量距离的时间演变来量化转移动力学,在所有情况下,在所有情况下,跟踪距离的单调减少随着越来越多的时间而暗示激动的距离马尔科维亚动态。

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