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The Regularities of Electrolytic Dissociation of 1,3-Cyclobutanedicarboxylic acids

机译:1,3-环丁二酸羧酸的电解解离的规律

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摘要

The dissociation parameters for the dilute (0.0001-0.01M) solutions of cis and trans-1,3-cyclobutanedicarboxylic acids were determined with the aid of the original method for analysis the regularities of electrolytic dissociation of weak multibasic organic acids with the close values of the dissociation constants of separate steps (the effect of "overlapping" equilibria). The equations for determination the regions of predominance of various charged and uncharged forms of these acids were also described.
机译:借助于分析弱多元有机酸的电解解离的原始方法,确定了CIS和反式-1,3-环丁二酸二羧酸的稀释(0.0001-0.01M)溶液的解离参数,以分析弱多元有机酸的电解解离的正规方法单独步骤的解离常数(“重叠的”均衡“的效果)。还描述了确定这些酸的各种带电和不带电形式的优势区域的方程。

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