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EFFECTS OF HYDROGEN ADDITION ON THE FLAME SPEEDS OF NATURAL GAS BLENDS UNDER UNIFORM TURBULENT CONDITIONS

机译:氢添加对均匀湍流条件下天然气混合物火焰速度的影响

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Natural gas is the primary fuel for stationary, power-generation gas turbines, and it is necessary to understand its combustion characteristics under engine-relevant (turbulent) conditions. Since its composition varies depending on the fuel source, a natural gas surrogate (NG 18% C2+) and admixtures with H_2 have been utilized recently by the authors to aid chemical kinetics modeling using ignition delay times and laminar flame speed experiments. The present study focused on measuring turbulent flame speeds (displacement speeds) of natural gas (NG2) and methane with H_2 using a fan-stirred flame bomb. The apparatus is a closed, cylindrical chamber fitted with four radial impellers that generate a central spherical volume of homogeneous and isotropic turbulence with negligible mean flow. Schlieren imaging was used to visually track the growth of the spherically expanding turbulent kernels during the constant-pressure period. The turbulence levels were fixed at an average RMS intensity level of 1.5 m/s and at an integral length scale of 27 mm. Turbulent flame speeds (S_(T,0.1)) of NG2 blends were measured over a wide range of equivalence ratios between 0.7 and 1.3. S_(T,0.1) for the natural gas surrogate closely matched with those of methane for near-stoichiometric mixtures. However, preferential-diffusion effects (fuel effects) were observed under turbulent conditions for off-stoichiometric cases. The effects of hydrogen addition on the turbulent flame speeds of NG2 (25/75 and 50/50 (by volume) blends of H_2/NG2) were also investigated and were compared with the flame speeds reported in a recent paper by the authors (ASME GT2014-26742) on the effects of hydrogen addition to turbulent flame speeds of methane. The effect of the hydrogen addition was to increase the turbulent flame speed (by about a factor of two for 50% H_2 addition), although this effect was much more pronounced for the lean and stoichiometric mixtures. Interestingly, the flame speeds (both laminar and turbulent) of the CH_4 blends with H_2 were slightly larger than those for the NG2 blend at equivalent conditions, or about 10-20% larger at 50% H_2 addition. This behavior can be explained kinetically by the increased importance of the inhibiting reaction CH_3 + H (+M) <-> CH_4 (+M), where ethane oxidation produces more CH_3 radicals than methane at similar conditions.
机译:天然气是静止,发电燃气轮机的主要燃料,有必要了解其在发动机相关(湍流)条件下的燃烧特性。由于其组成根据燃料源而变化,因此作者最近利用了一种天然气替代(Ng 18%C2 +)和与H_2的混合物,以利用点火延迟时间和层状火焰速度实验​​辅助化学动力学建模。本研究专注于使用风扇搅拌的火焰炸弹测量天然气(NG2)和H_2的天然气(NG2)和甲烷的湍流火焰速度(位移速度)。该装置是封闭的圆柱形腔室,其配有四个径向叶轮,其产生均匀和各向同性湍流的中心球体积,其平均流动可忽略不计。 Schlieren成像用于在恒压期间在视觉上跟踪球形膨胀湍流粒的生长。湍流水平以1.5米/秒的平均RMS强度水平固定,整体长度为27mm。在0.7和1.3之间的宽范围的等效比中测量NG2共混物的湍流火焰速度(S_(T,0.1))。 S_(T,0.1)用于天然气替代物与近代化学计量混合物密切匹配。然而,在湍流条件下观察到优先扩散效应(燃料效应)以进行脱离化学计量案件。还研究了氢添加对NG2(25/75和50/50(按体积)的湍流速度的影响(25/75和50/50(体积)混合物),并与作者最近报告的火焰速度进行比较(ASME GT2014-26742)关于氢气的影响与甲烷的湍流火焰速度。氢添加的效果是增加湍流火焰速度(50%H_2加成约两个倍数),尽管这种效果对于瘦和化学计量的混合物更为显着。有趣的是,CH_4共混物的火焰速度(层状和湍流)与H_2的共混物略大于当量条件下的NG2共混物,或者在50%H_2加入约10-20%。这种行为可以通过抑制反应CH_3 + H(+ M) - CH_4(+ M)的重要性增加,其中乙烷氧化在类似条件下产生更多CH_3的基团。

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