首页> 外文会议>ASME turbo expo: turbine technical conference and exposition >EFFECTS OF HYDROGEN ADDITION ON THE FLAME SPEEDS OF NATURAL GAS BLENDS UNDER UNIFORM TURBULENT CONDITIONS
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EFFECTS OF HYDROGEN ADDITION ON THE FLAME SPEEDS OF NATURAL GAS BLENDS UNDER UNIFORM TURBULENT CONDITIONS

机译:均匀湍流条件下加氢对天然气掺混物火焰速率的影响

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Natural gas is the primary fuel for stationary, power-generation gas turbines, and it is necessary to understand its combustion characteristics under engine-relevant (turbulent) conditions. Since its composition varies depending on the fuel source, a natural gas surrogate (NG 18% C_2+) and admixtures with H_2 have been utilized recently by the authors to aid chemical kinetics modeling using ignition delay times and laminar flame speed experiments. The present study focused on measuring turbulent flame speeds (displacement speeds) of natural gas (NG2) and methane with H_2 using a fan-stirred flame bomb. The apparatus is a closed, cylindrical chamber fitted with four radial impellers that generate a central spherical volume of homogeneous and isotropic turbulence with negligible mean flow. Schlieren imaging was used to visually track the growth of the spherically expanding turbulent kernels during the constant-pressure period. The turbulence levels were fixed at an average RMS intensity level of 1.5 m/s and at an integral length scale of 27 mm. Turbulent flame speeds (St,o.i) of NG2 blends were measured over a wide range of equivalence ratios between 0.7 and 1.3. S_(T,0.1) for the natural gas surrogate closely matched with those of methane for near-stoichiometric mixtures. However, preferential-diffusion effects (fuel effects) were observed under turbulent conditions for off-stoichiometric cases. The effects of hydrogen addition on the turbulent flame speeds of NG2 (25/75 and 50/50 (by volume) blends of H_2/NG2) were also investigated and were compared with the flame speeds reported in a recent paper by the authors (ASME GT2014-26742) on the effects of hydrogen addition to turbulent flame speeds of methane. The effect of the hydrogen addition was to increase the turbulent flame speed (by about a factor of two for 50% H_2 addition), although this effect was much more pronounced for the lean and stoichiometric mixtures. Interestingly, the flame speeds (both laminar and turbulent) of the CH_4 blends with H_2 were slightly larger than those for the NG2 blend at equivalent conditions, or about 10-20% larger at 50% H_2 addition. This behavior can be explained kinetically by the increased importance of the inhibiting reaction CH_3 + H (+M) ↔ CH_4 (+M), where ethane oxidation produces more CH_3 radicals than methane at similar conditions.
机译:天然气是固定式发电燃气轮机的主要燃料,有必要了解在发动机相关(湍流)条件下的燃烧特性。由于其组成随燃料来源的不同而不同,因此作者最近利用天然气替代物(NG 18%C_2 +)和与H_2的混合物通过点火延迟时间和层流火焰速度实验​​来辅助化学动力学建模。本研究的重点是使用风扇搅拌式火焰炸弹测量H_2与天然气(NG2)和甲烷的湍流火焰速度(置换速度)。该设备是一个装有四个径向叶轮的密闭圆柱形腔室,这些叶轮产生的均质和各向同性湍流的中心球形体积的平均流量可忽略不计。 Schlieren成像用于在恒压期间直观地跟踪球形膨胀湍流核的生长。湍流水平固定为平均RMS强度水平为1.5 m / s,整体长度刻度为27 mm。 NG2混合物的湍流火焰速度(St,o.i)在0.7至1.3的较大当量比范围内测量。天然气替代品的S_(T,0.1)与接近化学计量混合物的甲烷替代品的S_(T,0.1)紧密匹配。但是,对于化学计量比不佳的情况,在湍流条件下观察到了优先扩散效应(燃料效应)。还研究了加氢对NG2湍流火焰速度(H_2 / NG2混合物的25/75和50/50(按体积计)的湍流火焰速度)的影响,并将其与作者最近发表的论文(ASME)中报道的火焰速度进行了比较。 GT2014-26742),研究了氢气对甲烷湍流火焰速度的影响。氢气的添加效果是增加了湍流的火焰速度(对于添加50%的H_2,其速度提高了大约两倍),尽管这种效果在稀薄和化学计量的混合物中更为明显。有趣的是,与H_2混合的CH_4共混物的火焰速度(层流和湍流)比在相同条件下的NG2共混物的火焰速度略大,或者在添加50%的H_2时,其火焰速度约大10-20%。可以通过抑制反应CH_3 + H(+ M)↔CH_4(+ M)的重要性增加来从动力学上解释这种现象,在相似的条件下,乙烷氧化比甲烷产生更多的CH_3自由基。

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