Screening of Metal Oxides to Promote CO_2 Adsorption Performance over Polyethyleneimine Incorporated Solid Adsorbents

摘要

Amine-modified solid sorbents have attracted extensive interests in post-combustion carbon capture for power plants. Among various amines, polyethyleneiemine (PEI) is likely to be the most effective and promising candidate. However, previous studies have mainly focused on examining various supports to increase PEI loading and then enhance CO_2 adsorption capacity. In this study, one rare earth element (Ce) and 6 first-row transition metals (from V to Cu) in the oxidation stales impregnated on PEI incorporated γ-AI_2O_3 were prepared and investigated as potential catalyst/promotor for base-catalyzed reaction. Thermodynamic analysis, including isothermal and quasi-static CO_2 adsorption tests, were implemented to evaluate the performances amongst the 7 metal oxides. The results showed that MnO_2, CeO_2 and Fe_2O_3 showed a better performance in isothermal CO_2 adsorption at 75°C. Upon quasi-static tests, the results also indicates that the peak adsorption temperatures (T_(peak. a)) of V_2O_5 and Cr_2O_3 shifted to high temperature region, whilst opposite behavior of MnO_2 was observed. In preliminary study, density functional theory (DFT) was also adopted to assist the screening of metal oxide in terms of bond length and adsorption energies.