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Minimizing Mercury Pollution During Gold Ore Processing

机译:在金矿加工过程中最小化汞污染

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Mercury-bearing minerals are commonly associated with gold ores. One of the main potential sources of mercury air emissions at gold ore processing facilities has historically been from carbon regeneration kiln stacks. In view of this potential, air pollution controls are required at these facilities. Elution of the carbon, then, is one of the keys to minimizing mercury emissions. Sodium cyanide, sodium hydroxide, and acetic acid have been studied as eluting agents; eluant type and concentration, temperature, and time of elution are key parameters. With sodium cyanide and caustic as eluants, optimal temperature was in the range of 80°-90°C. After 24 hours of elution, about 95% of the Hg(CN)_(2(aq)) was eluted at 80°C. Acetic acid is an excellent and effective eluant of mercury cyanide. After about 4 hours of elution at 80°C with 10 vol% acetic acid at 3-4 bed volumes/hr, about 85% of the adsorbed Hg was stripped, while only about 0.2% of the Au(CN)_2~- and Ag(CN)_2~- was eluted.
机译:含汞矿物通常与黄金矿石有关。黄金矿石加工设施中汞空气排放的主要潜在潜在来源之一历史来自碳再生窑堆。鉴于这种潜力,这些设施需要空气污染控制。然后,碳的洗脱是最小化汞排放的键之一。已经研究了氰化钠,氢氧化钠和乙酸作为洗脱剂;洗脱型和浓度,温度和洗脱时间是关键参数。含有氰化钠和腐蚀性作为洗脱液,最佳温度在80°-90℃的范围内。洗脱24小时后,在80℃下洗脱约95%的Hg(CN)_(2(aq))。醋酸是氰化汞的优异且有效的溶剂。在80℃下在8-4张床体积/小时的10体积乙酸的80℃洗脱后,剥离约85%的吸附Hg,而仅约0.2%的Au(CN)_2〜 - 和AG(CN)_2〜 - 被洗脱。

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