Removal of sulfamethoxazole and erythromycin from aqueous solution by O_3/H_2O_2

摘要

The performance of sulfonamide and macrolide antibiotics in a spiked water removed by O_3 and O_3/H_2O_2 was evaluated uder different conditions such as ozone dosage, pH and H_2O_2/O_3 mole ratio. The results showed that O_3 and O_3/H_2O_2 were proved to be effective to oxdize sulfamethoxazole of sulfonamides containing the aromatic ring and erythromycin of macrolides, which were built of mostly saturated hydrocarbon structure, and O_3 was preferentially to oxidize sulfamethoxazole. With the reaction time of 30 min, when the ozone cocentrations were 2mg/L and 3mg/L, sulfamethoxazole and erythromycin removal efficiency was 93% and 91%, respectively. The sulfamethoxazole and erythromycin were removed completely within 30 min with ozone 6 mg/L. Degradation of sulfamethoxazole containing unsaturated C-C bonds occured easier at low pH only by O_3. Degradation of erythromycin with fully saturated structure was difficult, but the improved removal efficiency could be obtained at higher pH. The high concentratins of H_2O_2 to ozonation was favor to remove those antibiotics. At the 0.5 mole ratio of H_2O_2/O_3, the highest removal efficiency could be reached for all the antibiotics.