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Growth of Large Grain Polycrystalline Silicon Thin Film on Soda-lime Glass at Low Temperature for Solar Cell Applications

机译:低温下钠钙玻璃大谷物多晶硅薄膜的生长太阳能电池应用

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High quality polycrystalline silicon (poly-Si) thin film solar cell was successfully fabricated on soda-lime glass substrates by electron beam (Ebeam) evaporation at low processing temperature. The initial poly-Si seed layer (p~+-type 0.5 urn thick) was grown via the aluminum induced crystallization (AIC) method at 450°C. Prominent interdiffusion and Si crystallization have been observed. X-ray diffraction (XRD) shows that (111) is the dominating crystalline orientation. Post annealing at 450°C for six hours has produced densely packed Si grains with dimension of more than 10 μm in the plane of the film. Non-destructive Raman spectroscopy reveals the remarkable crystalline improvement for samples after thermal treatment. After removing the top diffused Al by chemical means, an absorber layer (p-type) of 0.9 μm thick was subsequently deposited onto the seed layer by Ebeam evaporation at 500 °C. Transmission electron microscopy (TEM) confirmed good homo-epitaxial growth. Without breaking the high vacuum, an n-type amorphous Si (a-Si) layer (0.7 μm thick) was coated onto the absorber layer to form p-n junction. The corresponding Ⅰ-Ⅴ characteristics suggest that our low temperature processing technique is applicable for production of poly-Si thin film solar cell on low cost substrates.
机译:在低加工温度下通过电子束(eBeam)蒸发在钠钙玻璃基板上成功地制造了高质量的多晶硅(Poly-Si)薄膜太阳能电池。通过铝诱导的结晶(AIC)方法在450℃下生长初始聚-Si种子层(P +型型0.5 urn厚)。已经观察到突出的相互积分和Si结晶。 X射线衍射(XRD)表明(111)是主导的结晶取向。在450°C时退火六小时在薄膜的平面中产生了密集的填充Si晶粒,尺寸超过10μm。非破坏性拉曼光谱揭示了热处理后样品的显着结晶改善。通过化学方法去除顶部扩散Al之后,随后通过在500℃下通过Ebeam蒸发沉积0.9μm厚的吸收层(p型)。透射电子显微镜(TEM)证实了良好的同性全角生长。在不破坏高真空中,将N型无定形Si(A-Si)层(0.7μm厚)涂覆到吸收层上以形成p-n结。相应的Ⅰ-n-n特性表明,我们的低温处理技术适用于生产低成本基材上的多Si薄膜太阳能电池。

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