Solvent-Free Stereoselective Synthesis of (E)-Ethyl-3-Aryl-Acrylates via Wittig Reaction of Arsonium Ylide by Grinding

机译：通过磨削通过芳香镁ylide的Wittig反应的（e） - 乙基-3-芳基 - 丙烯酸溶剂的无溶剂立体选择性合成

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摘要

A solvent-free process for the stereoselective preparation of (E)-ethyl-3-aryl-acrylates by grinding is described. Its advantages are easy workup, mild reaction conditions, high yields, and environmental friendliness.

机译：描述了通过研磨的（E） - 乙基-3-芳基 - 丙烯酸酯的立体选择性制剂的无溶剂方法。其优点是易于处理，温和的反应条件，高收益率和环境友好性。

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《International Conference on Textile Engineering and Materials》|2013年||共4页
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作者
Wang Changqing; Yi Yanping; Li Jiamin; Xiao Daoan; Liang Hui; Mei Guangquan;
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中图分类 TH145.23-53;
关键词
Arsonium ylide; Acrylates; Wittig reaction; Stereoselective synthesis;

机译：芳纶岩石;丙烯酸酯;Wittig反应;立体选择合成;
入库时间 2022-08-21 12:27:57

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1. Novel Stereoselective Synthesis of (E)-α,β-Unsaturated Esters by the Tandem Reaction of Deprotonation-Oxidation-Wittig Reaction from Phosphonium and Arsonium Salt [J] . 中国化学快报（英文版） . 2003,第003期

机译：Ph和son盐的去质子-氧化-威蒂希反应的串联反应新型立体选择性合成（E）-α，β-不饱和酯
2. Synthesis of α-seleno substituted semistabilized arsonium ylide and its Wittig reaction [J] . 中国化学快报（英文版） . 1998,第002期

机译：α-硒基取代的半稳定内鎓盐的合成及其Wittig反应
3. Highly Stereoselective Synthesis of trans-l,2-Cyclopropane Derivatives from Semistabilized Arsonium Ylides by Phase-Transfer-Catalysis Reactions [J] . Huihui Wang, Yali Chen, Weiguo Cao, Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2008,第24期

机译：通过相转移催化反应从半稳定的砷化Y中高度立体选择性地合成反式1,2-环丙烷衍生物
4. Solvent-Free Stereoselective Synthesis of (E)-Ethyl-3-Aryl-Acrylates via Wittig Reaction of Arsonium Ylide by Grinding [C] . Wang Changqing, Yi Yanping, Li Jiamin International Conference on Textile Engineering and Materials . 2013

机译：通过研磨通过芳烃ylide的Wittig反应，无溶剂立体选择合成（e） - 乙基-3-芳基 - 丙烯酸酯
5. Part I. Asymmetric synthesis of bicyclic analogues of risedronate as molecular probes of the mechanism of action of bisphosphonate antiosteoporotic drugs and potentially more efficacious antiosteoporotic agents. Part II. Facile preparation and functionalization of chiral stabilized ylides from common chiral auxiliaries using the Bestmann ylide and their use in Wittig reactions. Part III. Asymmetric organocatalysis: 1. An investigation of alpha-hydroxylation of aldehydes; 2. Synthesis of a novel camphor-based alpha-aminotetrazole organocatalyst. [D] . Song, Xinyi. 2007

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机译：通过氟膦酰基氟化物的Wittig反应合成四取代烯烃的E / Z选择性的来源：在烷氧基醛反应中观察到的低立体切性的解释

Solvent-Free Stereoselective Synthesis of (E)-Ethyl-3-Aryl-Acrylates via Wittig Reaction of Arsonium Ylide by Grinding

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