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Determination of ascorbic acid based on Gold nanoparticles-L-alanine/GCE

机译:基于金纳米颗粒-L-丙氨酸/ GCE的抗坏血酸测定

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A Gold nanoparticles-L-alanine modified glass electrode has been successfully fabricated by using layer-by-layer self-assembly technology and used for determination of ascorbic acid. First, the clean electrode was immersed into L-Alanine solution to acquire a L-Alanine film on the surface of GCE and dried at room temperature, then the gold colloid was dipped onto the L-Alanine film. The electrochemical behaviors of ascorbic acid at the modified electrode were investigated by cyclic voltammetry and current-time techniques. The results showed that the sensor produced high sensitivity and good stability to ascorbic acid and the current was linear with the concentration of ascorbic acid in the range of 1.20×10~(-5) to 1.60×10~(-4) mol/L with a detection limit of 1.00× 10~(-5) mol/L.
机译:通过使用层 - 逐层自组装技术成功制造了金纳米颗粒-1-丙氨酸改性玻璃电极,用于测定抗坏血酸。首先,将清洁电极浸入L-丙氨酸溶液中以在GCE的表面上获取L-丙氨酸膜并在室温下干燥,然后将金胶体浸入L-丙氨酸膜上。通过循环伏安法和当前技术研究改性电极处的抗坏血酸的电化学行为。结果表明,传感器产生高灵敏度和对抗坏血酸的良好稳定性,电流与抗坏血酸浓度为1.20×10〜( - 5)至1.60×10〜(-4)Mol / L的线性检测限为1.00×10〜(-5)mol / l。

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