Determination of platinum in waste platinum-loaded carbon catalyst samples using Teflon pressure vessel-assisted sample digestion and ICP-OES

摘要

A novel method for the determination of platinum in waste platinum-loaded carbon catalyst samples was established by inductively coupled plasma optical emission spectrometry after samples digested by Teflon pressure digestion vessel with aqua regia. Such experiment conditions were investigated as the influence of sample dissolution methods, digestion time, digestion temperature and interfering ions on the determination. Under the optimized conditions, the limit of detection (LODs) of Pt for tested solution was 15 ng mL~(-1). The relative standard deviations (RSDs) for Pt was 2.35 % (C_(pt) = 5 mg L~(-1), n = 7). The linear range of calibration graph for Pt was 0 ~ 150.00 mg L~(-1). The proposed method was applied to determine the practical samples with good recoveries and satisfactory results.