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Rheological properties of flaxseed gum solutions with NaCl or CaCl_2 addition

机译:用NaCl或CaCl_2添加亚麻籽胶溶液的流变性质

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The objective of this work was to evaluate the effect of NaCl and CaCl_2 salts addition, at a fixed ionic strength (150 mM), on the rheological properties of flaxseed gum (FG) solutions. FG was extracted from seeds by an aqueous extraction process and rheological properties (steady and dynamic measurements) of FG solutions were evaluated at three different gum concentrations (1, 1.5 and 2% w/w) without and with salts addition. Intrinsic viscosity of solutions (0.004-0.05% w/v) was also determined. FG solutions exhibited a shear thinning behavior without yield stress. Flow curves were fitted to the power law model, being that the salts addition led to an increase in flow behavior index (n) and a decrease in consistency index (k) values at the same FG concentration. The increase of FG concentration led to a higher viscosity (higher k values) and pseudoplasticity (lower n values). Intrinsic viscosity of FG solutions decreased with the salts addition, which is in agreement with results found by flow curves. In addition, a typical behavior of a solution (G" > G') and “weak gel” properties (G’ slightly greater than G") were observed at lower and higher FG concentration, respectively, for FG solutions without and with addition of salts. Samples without salts addition showed more pronounced elastic and viscous character than the solutions with salts addition. During the heating process, it was observed that the salts addition stabilized the network formed (G' increased), which was thermoirreversible. In general, it was not observed differences between rheological properties with mono or divalent (with different ionic radius) salts addition, which can be associated to an electrostatic screening between the negatively charged groups of FG and the positive salt ions.
机译:本作作品的目的是评估NaCl和CaCl_2盐的作用,在固定的离子强度(150mm)上,在亚麻籽胶(FG)溶液的流变性质上。通过通过种子从种子中提取FG,并在三种不同的胶浓度(1,1.5和2%w / w)下评价FG溶液的流变性(稳态和动态测量),而没有盐。还测定溶液的固有粘度(0.004-0.05%w / v)。 FG解决方案表现出剪切稀释行为而没有屈服应力。流量曲线安装在电力法模型上,作为盐的加法导致流动性指数(N)的增加,并在相同的FG浓度下降低一致性指数(k)值。 FG浓度的升高导致粘度较高(k值越高)和假塑性度(下N值。 FG溶液的固有粘度随着盐的添加而降低,这与流量曲线发现的结果一致。此外,在较低且较高的FG浓度下,对于FG溶液,典型地观察到溶液(G“> G')和”弱凝胶“性质(G'略大于g”),用于FG溶液,没有并加入盐。没有盐的样品添加显示比具有盐的溶液更明显的弹性和粘性性质。在加热过程中,观察到盐添加稳定的盐(G'增加),其是热磨蚀的。通常,未观察到流变性质与单级或二价(具有不同离子半径)的流变性质的差异,这可以与阳性FG和正盐离子之间的静电筛选相关联。

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